Aimco Brakes MSDSPulstar Fluid User Manual

							  
 
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SAFETY DATA SHEET 
 
In accordance with Commission Regulation (EU) 2015/830 of 28 May 2015 
Amending  Regulation (EC)  No  1907/2006  of the  European  Parliament  and  of the  Council  on 
the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH)  Compilation Date: 30 June 2011 
Revision Date: 4 March 2016   
SECTION 1: IDENTIFICATION OF THE SUBSTANCE / MIXTURE AND OF THE COMPANY / UNDERTAKING 
1.1 Product identifier 
・Trade name  : PULSTAR OIL 
・Designation  : Trimethylol propane tri-fatty acid ester containing additives 
・Product code : 998-700-0 for 1L container    998-701-0 for 5L container 
998-702-0 for 10L container  998-703-0 for 20L container 
1.2 Relevant identified uses of the substance or mixture and uses advised against 
・Relevant identified uses : Industrial uses (SU3) ; Lubricants, greases, release products (PC24) 
Industrial lubricant oil for hydraulic impulse tools 
・Pulstar Oil should not be used for any other purpose than the identified use. 
1.3 Details of the Supplier of the Safety Data Sheet  
・Manufacturer  : URYU SEISAKU, LTD. 
1-2-11, Fukae-Minami, Higashinari, Osaka, 537-0002 Japan. 
・Telephone   : +81-6-6973-9415 
・Fax   : +81-6-6972-0346 
・email (SDS questions)  : [email protected] 
・Supplier   : Local supplier 
     Address of local supplier 
・email   : email address of local supplier 
1.4 Emergency telephone number 
 ・Emergency telephone : +81-6-6973-9415  Only available during the following office hours 
・Opening hours : between 8.30 a.m. – 5.00 p.m. JST  Mon. – Fri. 
    JST = UTC + 9 hours / + 8 hours during summer time 
・Languages  : Japanese or English 
・Supplier  : Local supplier 
・Emergency telephone : Telephone number of local supplier         (opening time                  ) 
・Language  : (Local language) 
 
SECTION 2. HAZARDS IDENTIFICATION 
2.1 Classification of the substance or mixture 
・Classification according to Regulation (EC) No 1272/2008 
PULSTAR OIL is not classified as hazardous. 
WARNING 
  Pulstar Oil should only be handled by specially trained personnel. 
2.2 Label elements 
・Label elements 
The overall conclusion in accordance with Commission Regulation (EU) No 453/2010 of 20 May 2010 (REACH) is that there 
are no hazardous classifications associated with Pulstar Oil in respect to physical, health and environmental considerations. 
・Hazard pictograms  : Void 
・Signal word   : No signal word 
・Hazard statements  : No known significant effects or critical hazards. 
・Precautionary statements 
P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. – No smoking. 
P233 Keep container tightly closed. 
P280 Wear protective gloves / protective clothing / eye protection / face protection. 
 
 
 
 
 
P301+P330+P331 IF SWALLOWED: Rinse mouth.    Do NOT induce vomiting. 
P302+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing.  Rinse skin with water / shower. 
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. 
P305+P351+P338 IF IN EYES: Rinse continuously with water for several minutes. 
Remove contact lenses if present and easy to do, continue rinsing. 
 
 
 
 
     
						

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   2.3 Other hazards 
・Safety hazards  : The product is not classified as flammable, but will burn. 
・Health hazards  : The product is not expected to be a health hazard when used under normal conditions. 
Prolonged or repeated exposure to skin may cause skin dryness or cracking. 
・Environmental hazards: The product is not classified as hazardous for the environment. 
           Further information can be found in section 8.   
SECTION 3. COMPOSITION / INFORMATION ON INGREDIENTS 
3.1 Substances 
        The product is a mixture.    See 3.2 for details. 
3.2 Mixtures 
CAS No. EC No. % by Weight Name Classification according to 
Regulation (EC) No. 1278/2008 
68002-79-9 268-093-2 ≥90 
Fatty acids, C14-C18 and C16-C18 
unsatd., triesters with 
trimethylolpropane 
Not classified as hazardous 
860769-31-9 NA > 9 Oxirane, 2-ethyl-homopolymer Not classified as hazardous 
51311-17-2 257-131-3 > 1 Carbon fluoride Not classified as hazardous 
 Supplementary hazard information : Not applicable   
SECTION 4. FIRST AID MEASURES 
4.1 Description of first aid measures 
・General note 
The product is not expected to be a health hazard when used under normal condition. 
・Following inhalation 
 Remove the victim to fresh air and keep him / her warm and at rest.  
 Loosen tight parts of clothes. 
 Give oxygen in the case of breathing disorders.    
 If not breathing: ensure  that  there  is  no  obstruction  to  breathing  and  administer artificial respiration by  trained 
personnel.  If unconscious: place in the recovery position and get medical attention. 
・Following skin contact 
 Immediately remove contaminated clothing and wash affected skin with soap and water. 
 Do not use solvents or thinners as skin cleaning agents. 
・Following eye contact 
 Check for and remove any contact lenses.    
 Flush immediately with plenty of water while lifting the upper and lower eyelids until irritation subsides.  
 Continue to rinse for at least 15 minutes and get medical attention. 
        Note: Do not use a stream of water which is too strong, it may damage the cornea. 
・Following ingestion 
 Immediately wash out mouth with water. 
 If swallowed, get prompt medical attention. 
 Do not induce vomiting – increased aspiration risk. 
 When spontaneous vomiting occurs, keep the victim leaning forwards with his/her face directed to the ground.  
 If the victim is conscious, let him / her drink approx. 200mL of water. 
・Self-protection of the first aider 
 No action shall be taken involving any personal risk or without suitable training.  
 A person providing first aid in the area where vapours / mists concentration is unknown should be equipped with the 
appropriate respiratory protection. 
  4.2 Most important symptoms and effects, both acute and delayed 
 No known significant effects or critical hazards are observed. 
4.3 Indication of any medical attention and special treatment needed 
 Do not induce vomiting and do not administer anything orally to an unconscious person. 
 Show the safety data sheet to the medical staff.    
 A person providing first aid in the area where vapours / mists concentration is unknown should be equipped with the 
appropriate respiratory protection. 
      ・Note for doctors 
Treat symptomatically. 
 
 
      
						

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  SECTION 5. FIREFIGHTING MEASURES 
5.1 Extinguishing media 
・Suitable extinguishing media : Foam, dry powders, carbon dioxide (CO2), sand 
・Unsuitable extinguishing media : Water jet – it may cause splattering and spread the fire. 
Note : Simultaneous use of foam and water on the same surface is to be avoided as water destroys the foam. 
5.2 Special hazards arising from the substance or mixture 
 Hazardous gases produced in fire include carbon monoxide. 
 Avoid smoke inhalation during firefighting. 
5.3 Advice for firefighters 
・Fire fighting procedures 
 Clear fire area of all non-emergency personnel.  
 Remove combustibles from fire.  
 Use powder type / foam type extinguisher(s) to extinguish an early fire.   
 Air insulation covered by sand / foam will be effective for a large fire.   
Note: Extinguish a fire from the windward side of the fire. 
・Protective equipment :  
 Firefighters should wear self-contained positive pressure breathing apparatus and full turnout gear. 
・Advice for firefighters 
 : Observe normal firefighting procedures.   
SECTION 6. ACCIDENTAL RELEASE MEASURES 
     6.1 Personal precautions, protective equipment and emergency procedures 
 Use protective equipments, see section 8.  
 Limit the access of bystanders to the endangered area until proper cleaning operations are finished.  
 In the case of great leakage, isolate the endangered area and prepare fire extinguishers.  
 Avoid contact with skin, eyes and clothing.  
 Do not inhale vapours or mists.    
 If release occurred in a closed area, ensure adequate ventilation.   
 Remove ignition sources, extinguish open fire and do not smoke.   
 Spilt oils can make surfaces slippery. 
     6.2 Environmental precautions 
 If possible and safe, stop or limit product release.  
 Limit spreading of the great leakages by embanking the area to avoid environmental contamination.  
 Prevent  from  spreading  or  entering  drains,  ditches,  waterways,  rivers  or  soil by  using  sand,  earth or  other  appropriate 
barriers. 
     6.3 Methods and material for containment and cleaning up 
 Cover up small spillage with non-flammable absorbent materials such as sand, earth, sawdust or rag and collect in an 
appropriate, closed, labelled waste bin. 
 Finish cleaning up by flushing the contaminated surface with water.  
 When collecting, use shovels which do not produce sparks.  
     6.4 Reference to other sections 
 See section 13 for information on disposal. 
 Observe all relevant local and international regulations.   
SECTION 7. HANDLING AND STORAGE 
7.1 Precautions for safe handling 
 Unpack the material at application site to avoid unnecessary handling of the product. 
 Keep work areas clean. 
 Handle container with care. 
 Keep away from heat or strong oxidising agents. 
 Never overheat or it will produce vapours or mists. 
 Use good ventilation. 
 Pay attention to leakage and spillage. 
 Cleanse skin thoroughly after contact, before breaks and meals and at the end of work period. 
7.2 Conditions for safe storage, including any incompatibilities 
 Keep container closed when not in use. 
 Store away from strong oxidising agents and combustible materials. 
 Do not store near ignition sources (heat, sparks, flame, hot surfaces or strong oxidants). 
 Keep container tightly closed (P233) in a dry, cool and well-ventilated place and protect from direct sunlight. 
        Note: The additives precipitate during storage.  
                         Shake the container vigorously to mix the additives into the base oil before use. 
 Safe storage temperature : 0℃∼40℃ 
 Container  : P234 Keep only in original container.          Keep container properly labelled. 
7.3 Specific end use (s) 
 Recommendations  : Not applicable 
 Industrial sector specific solutions : Not applicable    
						

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SECTION 8. EXPOSURE CONTROLS AND PERSONAL PROTECTION 
8.1 Control parameters 
 Occupational exposure limit (OEL) : Not established 
 Maximum permission concentration : Not established 
8.2 Exposure controls 
・Appropriate engineering controls 
 Good general ventilation should be sufficient to control airborne levels. 
 Ensure that eyewash stations and safety showers are close to the work area. 
・Hygiene measures 
 Wash hands at the end of each work shift and before eating, smoking, using lavatory.  
 Use appropriate skin cream to prevent drying of skin.    
 When using, do not eat, drink or smoke.    
 Do not smoke in work area. 
・Personal protective equipments 
 Eye / face protection : Tightly fitted goggles or safety glasses with side shields 
 Hand protection : Impermeable (chemical-, oil-resistant) gloves 
 Skin protection  : Impermeable boots, long-sleeved clothing etc. 
   ・Environmental exposure controls 
Minimise release to the environment.  
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES 
 9.1 Information on basic phisical and chemical properties  
 Physical state   : Liquid 
 Colour    : Dark grey 
 Odour    : Mild petroleum 
 Odour threshold   : Not established 
 pH    : Not measurable 
 Pour point    : Approx. -5℃ (23°F) 
 Boiling point / range    : No data 
 Flash point   : 264℃ (507.2°F) (Cleveland open cup) 
 Evaporation rate   : Not applicable 
 Flammability   : Not applicable 
 Vapour pressure   : Not applicable 
 Vapour density   : Not applicable 
 Relative density   : Approximately 0.93g/cm3 at 15℃ (59°F) 
 Solubility    : Insoluble in water / Soluble in solvents such as ether, chloroform and acetone 
 Partition coefficient (n-octanol/water) : No data 
 Auto-ignition temperature  : No data 
 Decomposition temperature  : No data 
 Kinematic viscosity   : Approx. 42 mm2/s at 40℃ (104°F) 
 Explosive properties   : Not applicable 
 Oxidising properties   : Not applicable 
9.2 Other information 
 No additional information   
SECTION 10. STABILITY AND REACTIVITY  
         10.1 Reactivity 
  If mixed with alkaline substance and heated, it will generate soap. 
        10.2 Chemical stability 
  Stable under recommended storage and handling conditions, see section 7. 
         10.3 Possibility of hazardous reactions 
  Under normal conditions of storage and use, hazardous reactions will not occur.  
        10.4 Conditions to avoid 
  Extremes of temperature and direct sunlight 
        10.5 Incompatible materials 
  Strong oxidising agents 
         10.6 Hazardous decomposition products 
  None   
SECTION 11. TOXICOLOGICAL INFORMATION 
Information given are based on data on the main component, trimethylolpropane trioleate. 
11.1 Information on toxicological effect 
Acute toxicity 
Expected to be of low toxicity. 
 LD50 oral (rat)   : > 2000mg / kg 
 LD50 oral (mouse)  : No data 
 LD50 oral (guinea pig)  : No data 
 LD50 oral (rabbit)  : No data 
 Other information on LD50 oral : The dose limit (56.3mL/kg) for a mouse did not kill any test mice. 
  
						

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 Irritation / Sensitisation 
Expected to be slightly irritating. 
 LC50 dermal   : No data – Expected to be slightly irritating. 
     Prolonged or repeated skin contact may irritate skin. 
 Patch test (24h) (visual check) : Negative 
 Microscope check  : Negative 
 Eye irritation   : May slightly irritate eyes as would any foreign material. 
 Other information on irritation :  Expected  to  be  of  low  irritation  to  skin  and  respiratory  system,  but  prolonged  or 
     repeated skin contact may irritate skin due to degrease. 
 LC50 inhalation   : No data Not expected to pose an inhalation hazard under conditions of  
     foreseeable use. 
 Corrosivity   : No data 
 Carcinogenicity   : Not classified under IARC. 
 Genotoxicity   : No data 
 Teratology   : No data 
SECTION 12. ECOLOGICAL INFORMATION 
Information given is based on data on the main component, trimethylolpropane trioleate. 
 
12.1 Toxicity 
  Trimethylol propane tri-fatty acid ester containing additives (base oil) 
 Toxicity to fish LC50 (96h)  : 5500 mg/L (zebra fish) 
 Toxicity to daphnia EC50 (48h) : EC0 (24h) = 1000mg/L (daphnia manga) 
 Other information  : EC0 (30min.) = 1000mg/L (Pseudomonas putida) 
 
12.2 Persistence and degradability 
 BOD = 72% (anaerobic sludge 50mg/L, 35 days) 
 COD = 78% (aerobic sludge 100mg/L, 28 days) 
 
12.3 Bio accumulative potential No data – Not expected to bioaccumulate in aquatic organisms. 
  log P = approx. 25 
  Log P of approx. 7 or over hardly solve in water and is expected to accumulate in 
     aquatic organisms. 
12.4 Mobility on soil   Liquid under most environmental conditions.    Floats on water. 
12.5 Results of PBT and vPvB assessment Not PBT and not vPvB 
12.6 Other adverse effects   : No known significant effects or critical hazards. 
 
SECTION 13. DISPOSAL CONSIDERATIONS 
13.1    Waste treatment methods 
         The information in this section contains generic advice and guidance. The list of relevant Identified Uses in Section 1 should be 
consulted for any available use-specific information provided in the Exposure Scenario(s). 
 Recommendations for product : No special considerations required 
 Recommendations for container : Empty packaging should be completely drained. 
 LoW code 
・Pulstar Oil  : 13 02 05 – Mineral-based non-chlorinated lubricating oils 
・Containers : 15 01 02 – Plastic packaging for 1L-container, 5L-container and 10L-container 
  15 01 04 – Metallic packaging for 20L-container 
 Hazardous waste 
 To  present  knowledge  of  the  manufacturer,  this mixture is not  regarded  as  hazardous  waste  as defined  by  
Directive 2008/98/EC of the European Parliament and of the Council of 19 November 2008 on waste. 
 Sewage disposal shall be discouraged. 
 Final  decisions  on  the  appropriate  waste  management  method,  in  line  with  regional, national  and  European 
legislation, and possible adaption to local conditions, remains the responsibility of the waste treatment operator. 
 
SECTION 14. TRANSPORT INFORMATION 
14.1 UN number 
  ADR/RID  Not regulated  
  AND/ADNR Not regulated 
  IMDG  Not regulated 
  IATA  Not regulated 
14.2 UN proper shipping name 
  ADR/RID  None  
  AND/ADNR None 
  IMDG  None 
  IATA  None 
14.3 Transport hazards class(es) 
  ADR/RID  Not regulated  
  AND/ADNR Not regulated 
  IMDG  Not regulated 
  IATA  Not regulated  
						

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14.4 Packing group 
  ADR/RID  Not regulated  
  AND/ADNR Not regulated 
  IMDG  Not regulated 
  IATA  Not regulated 
14.5 Environmental hazards  
  ADR/RID  Not regulated  
  AND/ADNR Not regulated 
  IMDG  Not regulated 
  IATA  Not regulated 
14.6 Special precautions of use 
 No fire / No smoking 
 This mixture is not classified as flammable, but will burn, see sections 2 & 9. 
 Secure container firmly to prevent damage due to drop / shock etc.   
 Ensure that no rust or corrosion on container is evident, and no leakage before transport. 
14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code 
  Not applicable   
SECTION 15.REGULATORY INFORMATION 
15.1 Safety, health and environmental regulations/legislation specific for the substances or mixture  
This mixture is not classified according to Regulation (EC) No 1272/2008 of the European Parliament and of the 
Council of 16  December 2008 on  classification, labelling  and  packaging  of  substances  and  mixtures,  amending 
and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006. 
15.2 Chemical safety assessment 
・VOC contents : 0% 
・Japan Sewerage Act : Mineral oil sewerage discharge regulation (5mg/L) 
・Exposure scenarios : An extension of the SDS with exposure scenarios is not necessary because 
 the mixture is not classified as hazardous.   
SECTION 16. OTHER INFORMATION 
Abbreviations and acronyms in the safety data sheet 
  JST : Japanese Standard Time (=UTC +9) 
UTC : Universal Time Coordinated 
pH  : a measure of the acidity or basicity of an aqueous solution 
LD50 : Lethal Dose to 50% of a test population (Median lethal dose) 
LC50 : Lethal Concentration to 50% of a test population 
ECx  : Concentration at which x% inhibition of growth or growth rate is observed 
IARC : International Agency for Research on Cancer 
BOD : Biochemical Oxygen Demand 
COD : Chemical Oxygen Demand 
Koc  : Organic carbon absorption (coefficient) 
log P : Partition coefficient 
LoW : List of Wastes 
PBT : Persistent, Bioaccumulative and Toxic 
vPvB : Very Persistent and Very Accumulative 
ADR : Agreement of Dangerous Goods by Road 
RID  : International carriage of Dangerous Goods by Rail 
ADNR : Regulation for the Carriage of Dangerous Substances on the Rhine 
IMDG : International Maritime Dangerous Goods Code 
IATA : International Air Transport 
VOC : Volatile Organic Compounds 
・Source of information 
Information contained herewith is based on the information from raw material deliverers and  
URYU measurement test data. 
・Update Records 
2.1 29 March, 2013 : Section 2. Hazards Identification - Label Elements 
3.1  4 March, 2016 : Updated according to EU Commission Regulation No. 453/2010 Annex II (CLP) 
    Section 3. Composition / Information on Ingredients 
 
 
 
  DISCLAIMER Information provided herein is considered to be accurate as of the date specified above. No warranty is made as to the accuracy or completeness of the data and information provided in this safety data sheet.    Information provided herein serves only as guidelines for safe work, use, storage and waste management. It cannot be considered as a warranty or quality certificate. This  information  applies  only  to  specific  material  designated  and  may  not  be suitable  for  such  material  used  in  combination  with  any  other  materials  or  in  any other manner not described in this document.  URYU  SEISAKU,  LTD., - Osaka,  Japan – shall  not  be  responsible  for  any  damage  or  injury  resulting  from  abnormal  use  of  the  material  and  from  any  failure  to adhere to recommendations.  －End of SDS－